Liberians are choosing a new president in a run-off vote between Vice-President Joseph Boakai and former international footballer George Weah.
Mr Weah, 51, won the first round, but did not secure the required 50% of the vote for an outright victory.
Legal challenges delayed the vote to replace Ellen Johnson Sirleaf, Africa’s first elected female president.
Liberia, which was founded by freed US slaves in the 19th Century, has not had a smooth transfer of power in 73 years.
Polls across Liberia opened at 08:00 GMT and will close at 18:00.
More than two million people are eligible to cast their ballots.
Mr Boakai, 73, has been Liberia’s vice-president for 12 years but does not seem to enjoy the support of his boss, the BBC’s Umaru Fofana reports from the capital, Monrovia.
The candidate has described himself as being like a limousine idly parked for years in a garage and who is now ready to hit the road.
Mr Weah, the former world footballer of the year, is hoping for a third time lucky.
He defeated Ms Johnson-Sirleaf in the first round in 2005 but lost to her in the subsequent run-off. In the following election run-off, in 2011, when he ran as a running mate to the opposition candidate, his coalition boycotted the vote, citing irregularities.
A representative for the opposition Liberty Party, Charles Brumskine, who came third in October’s first round, challenged the result, saying it had been marred by “massive fraud and irregularities”.
But earlier this month the Supreme Court ruled that evidence of fraud was insufficient to merit a re-run of the opening round.
The verdict meant that the run-off – which had initially been set for 7 November – could go ahead.
